In particular, the electrodeposition technique has advantages over other processes due to its simplicity, low equipment cost, and the possibility of obtaining large-area thin films. Also, electrodeposition is an efficient and reliable technique for preparing ZnO nanocrystallites , nanowires [10, 11], and nanorods [5, 12]. One of the key elements to achieve high efficiency on nanostructured heterojunctions is the control on density, morphology, and crystallinity during growth . The resulting film surface morphology depends on a variety of parameters, like initial
solution, ion concentration, see more bath temperature, etc. . To improve nanostructure morphology of electrodeposited selleck products films, post-heat treatments are usually applied . In this sense, the evolution of optical and morphological properties with the annealing temperature for ZnO electrodeposited films on FTO was analyzed in a previous work . Recently, it has been found that the presence of a seed layer plays an important role in the properties of the nanostructured films grown on top of them by different methods such as hydrothermal synthesis [17–19]. This seed layer guaranteed a well-defined orientation
and alignment of the grown nanostructures, as well as optical property improvements due to their very low roughness and small particle size. Additionally, these primary oxide layers prevent direct hole combination when used in optoelectronic devices . In this work, the influence of different seed layers on the structural and optical properties of electrodeposited ZnO nanorods is analyzed. The transparent conductive oxide layer as seed layer was prepared by three different methods: (1) spin-coated ZnO, (2) direct current (DC) magnetron BTSA1 mouse sputtered ZnO, and (3) commercial ITO (In2O3:Sn)-covered Palbociclib concentration glass substrates. The ZnO growth process was also varied, taking into account previous studies on different electrodeposition procedures for nucleation and growth [5, 13].
Potentiostatic, galvanostatic, and pulsed-current electrochemical deposition methods were applied for each seed layer, analyzing their influence on the general properties of the obtained nanostructure. We have analyzed morphological and structural properties by scanning electron microscopy (SEM) and atomic force microscopy (AFM), and optical properties by transmission spectra. Optical bandgap was determined by Tauc’s plot. Methods ZnO spin coated on ITO A ZnO nucleant layer of 20-nm thickness and wurtzite crystalline structure was obtained by spin-coating technique. The substrates were 3 × 3-cm2 ITO (indium tin oxide)-sputtered glass (resistivity at room temperature, 15 Ω/cm2) from Asahi Glass Company (Tokyo, Japan). The solution used was a reagent-grade (RG) zinc acetate [Zn(CH3COO2) · 2H2O] dissolved in RG methanol in a 0.02-mol/l solution.